Unfortunately, Outlook lacks the ability to display all the message headers in a direct fashion. The companion to POPFile, Outclass allows you to classify messages within Outlook itself. (Outclass does not support other clients currently.)
If you only need to get to the the X-POPFile-Link occasionally, or you prefer POPFile to Outclass, you may yet be able to find the X-POPFile-link. In Outlook:
See also:
Should you find anything in the documentation that is incomplete, unclear, outdated or just plain wrong, please let us know and leave a note in the Documentation Forum.